The woman is called Dita Von Teese and she's a model, an actress and the world's foremost burlesque artiste
http://www.dita.net/
Her (now ex-)husband is one Marilyn Manson, a goth rock singer, whose most well-known song is probably "The Beautiful People" which you can listen to here:
He's also covered Tainted Love and Personal Jesus.
I actually really like the song in the video above, but haven't listened to much of his other stuff. It's not really my bag, but I don't mind the odd bit of rock every once in a while ... and it doesn't get much odder than him, does it ?